Substrate specificity of the protease that processes human interleukin-1 beta

J Biol Chem. 1990 Aug 25;265(24):14526-8.

Abstract

The substrate specificity of the protease which generates mature human interleukin-1 beta (IL-1 beta) from pro-interleukin-1 beta was investigated using synthetic peptide substrates and recombinant pro-IL-1 beta. The requirement of an L-aspartate in the P-1 position was confirmed together with the need for a small hydrophobic residue in the P-1' position (Gly or Ala). It was shown that the enzyme can tolerate conservative substitutions in the P-2 and P-2' positions. We found little difference in the enzyme's ability to cleave denatured and native pro-IL-1 beta, indicating that tertiary structure recognition is not involved in binding. The enzyme did, however, require a peptide of more than six amino acids for cleavage to occur. These results conclusively demonstrate the unusual specificity of this protease.

MeSH terms

  • Amino Acid Sequence
  • Humans
  • Interleukin-1 / genetics*
  • Interleukin-1 / metabolism
  • Kinetics
  • Molecular Sequence Data
  • Oligopeptides / chemical synthesis
  • Peptide Hydrolases / metabolism*
  • Protein Processing, Post-Translational*
  • Substrate Specificity

Substances

  • Interleukin-1
  • Oligopeptides
  • Peptide Hydrolases