Determination of organophosphorus pesticides in peanut oil by dispersive solid phase extraction gas chromatography-mass spectrometry

J Chromatogr B Analyt Technol Biomed Life Sci. 2011 Nov 15;879(30):3423-8. doi: 10.1016/j.jchromb.2011.09.016. Epub 2011 Sep 13.

Abstract

The organophosphorus pesticides including phorate, diazinon, tolclofos-methyl, fenitrothin, malathion, fenthion, isocarbophos, quinalphos and phenamiphos, in peanut oils were determined by liquid-liquid extraction coupled with dispersive solid phase extraction and gas chromatography-mass spectrometry (GC-MS). The mixture of multi-walled carbon nanotubes and alumina was used as adsorbent in dispersive solid phase extraction. The effects of some experimental conditions, such as types of multi-walled carbon nanotubes, amount of adsorbents and extraction time were examined. The limits of detection for the analytes were between 0.7 and 1.6 μg kg(-1). The obtained recoveries of the analytes in the samples were between 85.9 and 114.3% and relative standard deviations were lower than 8.48%.

MeSH terms

  • Arachis
  • Gas Chromatography-Mass Spectrometry / methods*
  • Linear Models
  • Nanotubes, Carbon / chemistry
  • Organothiophosphorus Compounds / analysis*
  • Organothiophosphorus Compounds / isolation & purification
  • Peanut Oil
  • Pesticides / analysis*
  • Pesticides / isolation & purification
  • Plant Oils / analysis
  • Plant Oils / chemistry*
  • Reproducibility of Results
  • Sensitivity and Specificity
  • Solid Phase Extraction / methods*

Substances

  • Nanotubes, Carbon
  • Organothiophosphorus Compounds
  • Peanut Oil
  • Pesticides
  • Plant Oils