Stability of levothyroxine injection in glass, polyvinyl chloride, and polyolefin containers

Am J Health Syst Pharm. 2011 Sep 15;68(18):1723-8. doi: 10.2146/ajhp100599.

Abstract

Purpose: The 24-hour stability of a levothyroxine solution admixed and stored in three common infusion containers and infused through polyvinyl chloride (PVC) tubing was evaluated.

Methods: Levothyroxine sodium 1-μg/mL injection prepared in glass bottles and PVC and polyolefin bags were assayed using high-performance liquid chromatography at 0, 1, 3, 6, 12, and 24 hours; samples drawn directly from the containers, as well as from the distal end of attached PVC tubing, were assayed. The area under the time-versus-concentration curve (AUC) for predicted and delivered doses was calculated; analysis of variance was used for comparison of the percentages of predicted and actual AUC values.

Results: The levothyroxine concentration was stable in glass bottles and polyolefin bags through 24 hours (mean ± S.D. percentage of initial concentration remaining, 103.5% ± 2.5% and 100.0% ± 2.9%, respectively). In the PVC infusion bags, the amount of drug decreased to 90% of the initial concentration within 1 hour and then rose and remained within acceptability limits. The levothyroxine concentration of the samples infused through PVC line from glass and polyolefin containers decreased after 1 hour by about 13%; the loss of the drug from the samples infused from PVC bags was higher (18%), presumably due to additive adsorptive effects. In all samples tested, the drug concentration rebounded and remained above 90% to the end of the study.

Conclusion: Levothyroxine sodium 1-μg/mL solution was stable for 24 hours in glass bottles and polyolefin bags but when stored in PVC bags, the concentration decreased by 10% after 1 hour.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Analysis of Variance
  • Area Under Curve
  • Chromatography, High Pressure Liquid
  • Drug Packaging
  • Drug Stability
  • Drug Storage
  • Glass / chemistry*
  • Pharmaceutical Solutions
  • Polyenes / chemistry*
  • Polyvinyl Chloride / chemistry*
  • Thyroxine / chemistry*
  • Time Factors

Substances

  • Pharmaceutical Solutions
  • Polyenes
  • PL 732
  • Polyvinyl Chloride
  • Thyroxine