[5,10,15,20-Tetra-kis(4-meth-oxy-phen-yl)porphyrinato-κN,N',N'',N'''](trifluoro-methane-sulfonato-κO)-iron(III)

Nan Xu; Douglas R Powell; George B Richter-Addo

doi:10.1107/S1600536811001395

[5,10,15,20-Tetra-kis(4-meth-oxy-phen-yl)porphyrinato-κN,N',N'',N'''](trifluoro-methane-sulfonato-κO)-iron(III)

Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 29;67(Pt 2):m268. doi: 10.1107/S1600536811001395.

Authors

Nan Xu¹, Douglas R Powell, George B Richter-Addo

Affiliation

¹ Department of Chemistry and Biochemistry, University of Oklahoma, 101 Stephenson Parkway, Norman, OK 73019-5251, USA.

Abstract

The title compound, [Fe(CF(3)O(3)S)(C(48)H(36)N(4)O(4))], is a five-coordinate iron(III) porphyrin complex with a trifluoro-methane-sulfonate anion as an axial ligand. The Fe(III) atom is displaced by 0.40 (1) Å towards the trifluoro-methane-sulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe-N(p) distance is 2.044 (2) Å and the Fe-O distance is 2.001 (2) Å.

Abstract

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