A multi-channel sensor based on 8-hydroxyquinoline ferrocenoate for probing Hg(II) ion

Lei Shi; Wei Song; Yang Li; Da-Wei Li; Kalen N Swanick; Zhifeng Ding; Yi-Tao Long

doi:10.1016/j.talanta.2011.02.024

A multi-channel sensor based on 8-hydroxyquinoline ferrocenoate for probing Hg(II) ion

Talanta. 2011 May 15;84(3):900-4. doi: 10.1016/j.talanta.2011.02.024. Epub 2011 Feb 23.

Authors

Lei Shi¹, Wei Song, Yang Li, Da-Wei Li, Kalen N Swanick, Zhifeng Ding, Yi-Tao Long

Affiliation

¹ Shanghai Key Laboratory of Functional Materials Chemistry & Department of Chemistry, East China University of Science and Technology, 200237, Shanghai, PR China.

PMID: 21482300
DOI: 10.1016/j.talanta.2011.02.024

Abstract

A new sensing molecule 8-hydroxyquinoline ferrocenoate (Fc-Q) which combines ferrocene and 8-hydroxyquinoline moieties was synthesized and applied as a multi-channel sensor for the detection of Hg(2+) ion. Fc-Q can coordinate with Hg(2+) to give colorimetric, fluorescent and electrochemical responses. Upon complexation with Hg(2+) ion, the characteristic absorption peak is red-shifted (Δλ=45 nm), the fluorescent intensity is quenched at 303 nm, and the oxidation peak is cathodic shifted (ΔE(1/2)=-149 mV). Quantitatively analyzed Hg(2+) ions at the range of ppb level could be achieved by electrochemical response. For the practical application of sensing Hg(2+) in real world water, Fc-Q modified screen-printed carbon electrodes were obtained for facile, sensitive, and on-site analysis of Hg(2+).