Ultrafast dynamics of excitons in semiconductor quantum dots on a plasmonically active nano-structured silver film

Nanotechnology. 2011 May 13;22(19):195704. doi: 10.1088/0957-4484/22/19/195704. Epub 2011 Mar 23.

Abstract

The excited state dynamics of core-shell type semiconductor quantum dots (QDs) of various sizes in close contact with a plasmonically active silver thin film has been demonstrated by using picosecond resolved fluorescence spectroscopy. The non-radiative energy transfer from the QDs to the metal surface is found to be of Förster resonance energy transfer (FRET) type rather than the widely expected nano-surface energy transfer (NSET) type. The slower rate of energy transfer processes compared to that of the electron transfer from the excited QDs to an organic molecule benzoquinone reveals an insignificant possibility of charge migration from the QDs to the metallic film.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Benzoquinones / chemistry
  • Energy Transfer
  • Fluorescence Resonance Energy Transfer / methods
  • Light
  • Metal Nanoparticles / chemistry*
  • Microscopy, Atomic Force / methods
  • Microscopy, Electron, Scanning / methods
  • Microscopy, Electron, Transmission / methods
  • Nanoparticles / chemistry
  • Nanotechnology / methods*
  • Quantum Dots*
  • Semiconductors*
  • Silver / chemistry*
  • Spectrometry, Fluorescence / methods
  • Time Factors

Substances

  • Benzoquinones
  • Silver
  • quinone