Dual-fluorophore ratiometric pH nanosensor with tuneable pKa and extended dynamic range

Analyst. 2011 May 7;136(9):1799-801. doi: 10.1039/c1an15042a. Epub 2011 Mar 18.

Abstract

Ratiometric pH nanosensors with tuneable pK(a) were prepared by entrapping combinations of two pH-sensitive fluorophores (fluorescein isothiocyanate dextran (FITC-D) and Oregon Green(®) dextran (OG-D)) and a reference fluorophore (5-(and-6)-carboxytetramethylrhodamine dextran (TAMRA-D)), in a biocompatible polymer matrix. Dual-fluorophore pH nanosensors permit the measurement of an extended dynamic range, from pH 4.0 to 7.5.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Biocompatible Materials / metabolism
  • Biosensing Techniques / methods*
  • Dextrans / chemistry
  • Fluorescein-5-isothiocyanate / analogs & derivatives
  • Fluorescein-5-isothiocyanate / chemistry
  • Fluorescent Dyes / chemistry*
  • Hydrogen-Ion Concentration
  • Ionophores*
  • Nanoparticles / chemistry
  • Nanotechnology
  • Polymers / chemistry*

Substances

  • Biocompatible Materials
  • Dextrans
  • Fluorescent Dyes
  • Ionophores
  • Polymers
  • fluorescein isothiocyanate dextran
  • Fluorescein-5-isothiocyanate