A well-defined silica-supported aluminium alkyl through an unprecedented, consecutive two-step protonolysis-alkyl transfer mechanism

Jérémie Pelletier; Jeff Espinas; Nghiem Vu; Sébastien Norsic; Anne Baudouin; Laurent Delevoye; Julien Trébosc; Erwan Le Roux; Catherine Santini; Jean-Marie Basset; Régis M Gauvin; Mostafa Taoufik

doi:10.1039/c0cc04986g

A well-defined silica-supported aluminium alkyl through an unprecedented, consecutive two-step protonolysis-alkyl transfer mechanism

Chem Commun (Camb). 2011 Mar 14;47(10):2979-81. doi: 10.1039/c0cc04986g. Epub 2011 Jan 21.

Authors

Jérémie Pelletier¹, Jeff Espinas, Nghiem Vu, Sébastien Norsic, Anne Baudouin, Laurent Delevoye, Julien Trébosc, Erwan Le Roux, Catherine Santini, Jean-Marie Basset, Régis M Gauvin, Mostafa Taoufik

Affiliation

¹ Chimie Organométallique de Surface/Laboratoire de Chimie, Catalyse, Polymères et Procédés (UMR-C2P2-5265 CNRS/ESCPE-Lyon/UCBL) ESCPE Lyon, F-308-43, Boulevard du 11 Novembre 1918, F-69616, Villeurbanne Cedex, France.

PMID: 21253632
DOI: 10.1039/c0cc04986g

Abstract

Impregnation of [(AliBu(3))(Et(2)O)] on partially dehydroxylated SBA-15 affords a mesoporous material bearing the well-defined single site surface aluminium species [(≡SiO)(2)Al(iBu)(Et(2)O)].