(Pyridino-15-crown-5-κN,O,O',O'',O''')bis-(thio-cyanato-κN)manganese(II)

Chengjuan Li; Zejing Feng; Dacheng Li; Daqi Wang

doi:10.1107/S160053680800679X

(Pyridino-15-crown-5-κN,O,O',O'',O''')bis-(thio-cyanato-κN)manganese(II)

Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 14;64(Pt 4):m557. doi: 10.1107/S160053680800679X.

Authors

Chengjuan Li¹, Zejing Feng, Dacheng Li, Daqi Wang

Affiliation

¹ School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, People's Republic of China.

Abstract

The title complex, [Mn(NCS)(2)(C(13)H(19)NO(4))] {systematic name: [3,6,9,12-tetra-oxa-18-aza-bicyclo-[12.3.1]octa-cosa-14(18),15,17-triene-κ(5)N,O,O',O'',O''']bis-(thio-cyanato-κN)manganese(I-I)}, was obtained by the reaction of MnCl(2)·4H(2)O and NaSCN with pyridino-15-crown-5. The Mn(2+) center has a distorted penta-gonal bipyramidal coordination geometry, coordinated by four O atoms and one N atom of the pyridino-15-crown-5 mol-ecule, and by the N atoms of the two NCS(-) ligands.