Utilization of Sc3N@C80 in long-range charge transfer reactions

Silke Wolfrum; Julio R Pinzón; Agustin Molina-Ontoria; Andreas Gouloumis; Nazario Martín; Luis Echegoyen; Dirk M Guldi

doi:10.1039/c0cc04159a

Utilization of Sc3N@C80 in long-range charge transfer reactions

Chem Commun (Camb). 2011 Feb 28;47(8):2270-2. doi: 10.1039/c0cc04159a. Epub 2010 Dec 15.

Authors

Silke Wolfrum¹, Julio R Pinzón, Agustin Molina-Ontoria, Andreas Gouloumis, Nazario Martín, Luis Echegoyen, Dirk M Guldi

Affiliation

¹ Department of Chemistry and Pharmacy and Interdisciplinary Center for Molecular Materials, Friedrich-Alexander-Universität Erlangen-Nürnberg, 91058 Erlangen, Germany. silke.wolfrum@chemie.uni-erlangen.de

PMID: 21157615
DOI: 10.1039/c0cc04159a

Abstract

Electron accepting Sc(3)N@C(80) promotes long-range charge transfer events evolving from photoexcited metalloporphyrins to afford radical ion pair states with lifetimes in the range of μs.