Tandem Michael addition/intramolecular isocyanide [3 + 2] cycloaddition: highly diastereoselective one pot synthesis of fused oxazolines

Chem Commun (Camb). 2010 May 21;46(19):3357-9. doi: 10.1039/c001617a. Epub 2010 Mar 25.

Abstract

A base-catalyzed tandem Michael addition/intramolecular isocyanide [3 + 2] cycloaddition of ethyl isocyanoacetate and Michael acceptors with tethered carbonyl groups is described. This reaction leads to the formation of fused oxazolines in a highly diastereoselective manner under very mild conditions.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cyanides / chemical synthesis*
  • Cyanides / chemistry
  • Cyclization
  • Molecular Structure
  • Oxazoles / chemical synthesis*
  • Oxazoles / chemistry
  • Stereoisomerism

Substances

  • Cyanides
  • Oxazoles