Phase separation of organic/inorganic hybrids induced by calcination: a novel route for synthesizing mesoporous silica and carbon materials

Sen Liu; Zhe Zhang; Haiyan Zhang; Yonglai Zhang; Shu Wei; Limin Ren; Chunyu Wang; Yinyan He; Fei Li; Feng-Shou Xiao

doi:10.1016/j.jcis.2010.02.008

Phase separation of organic/inorganic hybrids induced by calcination: a novel route for synthesizing mesoporous silica and carbon materials

J Colloid Interface Sci. 2010 May 15;345(2):257-61. doi: 10.1016/j.jcis.2010.02.008. Epub 2010 Feb 10.

Authors

Sen Liu¹, Zhe Zhang, Haiyan Zhang, Yonglai Zhang, Shu Wei, Limin Ren, Chunyu Wang, Yinyan He, Fei Li, Feng-Shou Xiao

Affiliation

¹ State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China.

PMID: 20189188
DOI: 10.1016/j.jcis.2010.02.008

Abstract

Mesoporous silica and carbon materials have been successfully synthesized via a novel calcination induced phase separation of organic/inorganic hybrids prepared from solvothermal polymerization of polyvinyl alcohol (PVA) and tetraethyl orthosilicate (TEOS) in dimethyl sulfoxide (DMSO). Combined characterizations of XRD, nitrogen isotherms, and TEM techniques show that the samples have worm-like mesostructures with uniform pore size distributions and large BET surface areas. (1)H NMR spectra reveal that ethanol was generated after the solvothermal treatments, indicating the polymerization of PVA and TEOS. Open mesopores of the desired silicas or carbons could be fabricated by calcining the hybrids in air and nitrogen, respectively. This route might open a new methodology to synthesize mesoporous materials.