A twofold interpenetrating porous metal-organic framework with high hydrothermal stability: structure and gas sorption behavior

Inorg Chem. 2009 Dec 21;48(24):11507-9. doi: 10.1021/ic901924z.

Abstract

A twofold interpenetrating polyhedron-based metal-organic framework with high hydrothermal stability was prepared using a rigid and bent C(2)-symmetric ligand containing two 3,5-benzenedicarboxylate units, which have large surface area and high uptake capacities for various gas molecules.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Alkynes / chemistry*
  • Benzene Derivatives / chemistry*
  • Copper / chemistry*
  • Ligands
  • Molecular Structure
  • Nitrogen / chemistry*
  • Organometallic Compounds / chemistry*
  • Porosity
  • Surface Properties

Substances

  • 1,3-bis(3,5-dicarboxylphenylethynyl)benzene
  • Alkynes
  • Benzene Derivatives
  • Ligands
  • Organometallic Compounds
  • Copper
  • Nitrogen