Skeletal rearrangement of all-carbon spiro skeletons mediated by a Lewis acid

Fei Zhao; Chao Wang; Lantao Liu; Wen-Xiong Zhang; Zhenfeng Xi

doi:10.1039/b914619a

Skeletal rearrangement of all-carbon spiro skeletons mediated by a Lewis acid

Chem Commun (Camb). 2009 Nov 21:(43):6569-71. doi: 10.1039/b914619a. Epub 2009 Sep 11.

Authors

Fei Zhao¹, Chao Wang, Lantao Liu, Wen-Xiong Zhang, Zhenfeng Xi

Affiliation

¹ Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.

PMID: 19865652
DOI: 10.1039/b914619a

Abstract

Mediated by AlCl(3), substituted spiro[4.5]deca-tetraenes underwent novel and selective skeletal rearrangement to generate indene derivatives in high to excellent yields.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Acids / chemistry*
Carbon / chemistry*

Substances

Acids
Carbon