X-ray absorption fine structures of uranyl(V) complexes in a nonaqueous solution

Koichiro Takao; Satoru Tsushima; Shinobu Takao; Andreas C Scheinost; Gert Bernhard; Yasuhisa Ikeda; Christoph Hennig

doi:10.1021/ic901487r

X-ray absorption fine structures of uranyl(V) complexes in a nonaqueous solution

Inorg Chem. 2009 Oct 19;48(20):9602-4. doi: 10.1021/ic901487r.

Authors

Koichiro Takao¹, Satoru Tsushima, Shinobu Takao, Andreas C Scheinost, Gert Bernhard, Yasuhisa Ikeda, Christoph Hennig

Affiliation

¹ Institute of Radiochemistry, Forschungszentrum Dresden-Rossendorf, P.O. Box 510119, 01314 Dresden, Germany. k.takao@fzd.de

PMID: 19754101
DOI: 10.1021/ic901487r

Abstract

The structures of three different U(V) complexes, [U(V)O(2)(salophen)DMSO](-), [U(V)O(2)(dbm)(2)DMSO](-), and [U(V)O(2)(saldien)](-), in a dimethyl sulfoxide (DMSO) solution were determined by X-ray absorption fine structure for the first time.