Zintl phase as dopant source in the flux synthesis of Ba(1-x)K(x)Fe(2)As(2) type superconductors

Chem Commun (Camb). 2009 Sep 7:(33):4965-7. doi: 10.1039/b910749e. Epub 2009 Jul 21.

Abstract

Use of the Zintl phase KSn as a source of potassium dopant in tin flux syntheses of Ba(1-x)K(x)Fe(2)As(2) allows for incorporation of large amounts of potassium with much less attack on reaction vessels compared to the use of elemental potassium as a reactant; it also enables further study of tin incorporation into the products.