Supramolecular chemistry of fluoroanions: selectivity in weak interactions

David Sémeril; Dominique Matt; Jack Harrowfield; Nate Schultheiss; Loïc Toupet

doi:10.1039/b906160f

Supramolecular chemistry of fluoroanions: selectivity in weak interactions

Dalton Trans. 2009 Aug 28:(32):6296-8. doi: 10.1039/b906160f. Epub 2009 Jul 1.

Authors

David Sémeril¹, Dominique Matt, Jack Harrowfield, Nate Schultheiss, Loïc Toupet

Affiliation

¹ Laboratoire de Chimie Inorganique Moléculaire et Catalyse, Université de Strasbourg, Institut de Chimie UMR 7177 CNRS-UdS, 1 rue Blaise Pascal, F-67008, Strasbourg Cedex, France.

PMID: 19655062
DOI: 10.1039/b906160f

Abstract

Interactions of a chiral, calixarene-based cationic Pd(II) catalyst with [BF(4)](-) and [PF(6)](-) anions have very different consequences, association with the former giving rise to capsule formation.