Physical and chemical quenching rates and their influence on stereoselective photooxygenation of oxazolidinone-functionalized enecarbamates

Marissa R Solomon; J Sivaguru; Steffen Jockusch; Waldemar Adam; Nicholas J Turro

doi:10.1039/b903848e

Physical and chemical quenching rates and their influence on stereoselective photooxygenation of oxazolidinone-functionalized enecarbamates

Photochem Photobiol Sci. 2009 Jul;8(7):912-5. doi: 10.1039/b903848e. Epub 2009 Mar 24.

Authors

Marissa R Solomon¹, J Sivaguru, Steffen Jockusch, Waldemar Adam, Nicholas J Turro

Affiliation

¹ The Department of Chemistry, Columbia University, New York, NY 10027, USA.

PMID: 19582265
DOI: 10.1039/b903848e

Abstract

Physical and chemical quenching rate constants were measured for the reaction of singlet oxygen with oxazolidinone-functionalized enecarbamates to investigate the role of vibrational deactivation in product stereoselectivity.