Abstract
In H(2)O-CHCl(3), the phosphonium borane [ortho-(Mes(2)B)C(6)H(4)(PMePh(2))](+) selectively complexes azide anions to afford ortho-(Mes(2)(N(3))B)C(6)H(4)(PMePh(2)) in which the boron-bound azide anion is stabilized by an interaction with the adjacent phosphorus atom.
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Azides / chemistry*
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Boranes / chemistry*
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Chelating Agents / chemistry*
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Chloroform / chemistry*
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Models, Molecular
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Molecular Conformation
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Organoplatinum Compounds / chemistry*
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Solvents / chemistry
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Water / chemistry*
Substances
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Azides
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Boranes
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Chelating Agents
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Organoplatinum Compounds
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Solvents
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Water
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Chloroform