Diffusion in two-dimensional colloidal systems on periodic substrates

Phys Rev E Stat Nonlin Soft Matter Phys. 2009 Apr;79(4 Pt 1):041407. doi: 10.1103/PhysRevE.79.041407. Epub 2009 Apr 27.

Abstract

We study the diffusive behavior of two-dimensional charged colloidal suspensions subjected to a sinusoidal substrate by means of Brownian dynamics simulations. We mainly focus on the dependence of the mean-square displacement on the substrate strength. Our findings show a variation in the particle diffusion due to a substrate-induced distortion of the dynamic cage of nearest-neighbor colloids. This mechanism leads to a transition from normal diffusion at short times to subdiffusion on intermediate time scales. However, at long times normal diffusion is recovered. We also show that the variation in the long-time self-diffusion coefficient may be associated with the freezing and re-entrant melting transitions.

Publication types

  • Research Support, Non-U.S. Gov't