Four-state switching characteristics of a gated molecular basket

Org Lett. 2009 Jun 18;11(12):2495-8. doi: 10.1021/ol9009392.

Abstract

The development of working molecular devices relies on the ability to extrinsically modulate function via structure. We have found that gated molecular basket 1 can be reversibly interconverted among four unique structural states (see above). Controlling the relative population of these states, the recognition characteristics of the basket can be finely tuned.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Copper / chemistry*
  • Crystallography, X-Ray
  • Magnetic Resonance Spectroscopy
  • Models, Molecular
  • Molecular Structure
  • Pyridines / chemistry*
  • Structure-Activity Relationship

Substances

  • Pyridines
  • Copper