ABT-737, a BH3 mimetic, induces glutathione depletion and oxidative stress

Cancer Chemother Pharmacol. 2009 Dec;65(1):41-54. doi: 10.1007/s00280-009-1001-1. Epub 2009 Apr 29.

Abstract

Purpose: This study assessed the role of oxidative stress and loss of glutathione in ABT-737-induced apoptosis.

Methods: Jurkat human acute lymphocytic leukemia cells and HeLa cells transfected with a tet-regulated Bcl-2 expression system were treated with ABT-737 or its less active stereoisomer. GSH concentrations, intracellular reactive oxygen species (ROS), caspase activation and apoptotic DNA fragmentation were measured.

Results: ABT-737 induced oxidative stress through decreased GSH and increased intracellular hydrogen peroxide and superoxide levels. Apoptotic DNA fragmentation and caspase activation were the consequences of this oxidative stress. Combining ABT-737 with ROS-inducing agents such as adaphostin or etoposide enhanced cell death.

Conclusions: These results demonstrate that inhibition of Bcl-2 causes a loss of GSH, an increase in ROS, caspase activation and subsequent apoptosis. Clinically, redox alterations as a consequence of Bcl-2 inhibition by ABT-737 should be considered in devising combination therapies with this novel agent or its derivatives.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Apoptosis / drug effects
  • Biphenyl Compounds / chemistry
  • Biphenyl Compounds / pharmacology*
  • Caspases / drug effects
  • Caspases / metabolism
  • DNA Fragmentation / drug effects
  • Glutathione / drug effects*
  • Glutathione / metabolism
  • HeLa Cells
  • Humans
  • Hydrogen Peroxide / metabolism
  • Jurkat Cells
  • Nitrophenols / chemistry
  • Nitrophenols / pharmacology*
  • Oxidation-Reduction
  • Oxidative Stress / drug effects*
  • Piperazines / chemistry
  • Piperazines / pharmacology
  • Proto-Oncogene Proteins c-bcl-2 / antagonists & inhibitors
  • Reactive Oxygen Species / metabolism
  • Stereoisomerism
  • Sulfonamides / chemistry
  • Sulfonamides / pharmacology*
  • Superoxides / metabolism
  • Transfection

Substances

  • ABT-737
  • Biphenyl Compounds
  • Nitrophenols
  • Piperazines
  • Proto-Oncogene Proteins c-bcl-2
  • Reactive Oxygen Species
  • Sulfonamides
  • Superoxides
  • Hydrogen Peroxide
  • Caspases
  • Glutathione