Conformation and disulfide bond formation of the constant fragment of an immunoglobulin light chain: effect of truncation at the C-terminal region

Biochemistry. 1991 Aug 6;30(31):7766-71. doi: 10.1021/bi00245a014.

Abstract

Constant fragments with different carboxyl terminals, CL(109-211), CL(109-207), and CL-(109-200), were prepared by limited carboxypeptidase P or Y proteolysis of the constant fragment, CL-(109-214), of a type lambda immunoglobulin light chain, and their conformations and stabilities, and formation of the disulfide bond from the reduced fragments, were studied. No change in conformation or stability was observed on removal of three residues from the C-terminal end. Removal of seven or more residues from the C-terminal end destabilized the CL fragment. The rate of disulfide bond formation from reduced CL(109-207) was about 7 times faster than that for CL(109-214). These findings suggest that elongation of the polypeptide chain at least beyond the 207th residue is necessary for folding of the CL fragment into a definite conformation.

MeSH terms

  • Amino Acid Sequence
  • Carboxypeptidases
  • Disulfides / analysis
  • Drug Stability
  • Humans
  • Immunoglobulin Constant Regions*
  • Immunoglobulin Light Chains* / isolation & purification
  • Immunoglobulin Light Chains* / urine
  • Kinetics
  • Molecular Sequence Data
  • Multiple Myeloma / urine
  • Protein Conformation
  • Thermodynamics

Substances

  • Disulfides
  • Immunoglobulin Constant Regions
  • Immunoglobulin Light Chains
  • Carboxypeptidases