Effect of phenazine compounds XR11576 and XR5944 on DNA topoisomerases

Cancer Chemother Pharmacol. 2009 Apr;63(5):889-901. doi: 10.1007/s00280-008-0812-9. Epub 2008 Aug 5.

Abstract

Purpose: Previous in vitro cleavage data showed that XR11576 and XR5944 stabilised topoisomerase I and topoisomerase II complexes on DNA in a dose-dependent fashion. However, some studies indicated a possible topoisomerase-independent mechanism of action for these drugs.

Methods: Three methods, the TARDIS assay, immunoband depletion and the K(+)/SDS assay have been used to assess topoisomerase complex formation induced by XR11576 or XR5944 in human leukaemic K562 cells.

Results: TARDIS and immunoband depletion assays demonstrated that XR11576 and XR5944 induced complex formation for both topoisomerase I and topoisomerase II (alpha and beta) in a dose- and time-dependent manner, following exposure times of 24 and 48 h at concentrations of 1 or 10 microM. The K(+)/SDS assay showed the formation of protein/DNA complexes after a 1 h exposure to 1 or 10 muM XR11576.

Conclusion: Our data confirm that XR11576 or XR5944 can form topoisomerase complexes, after long periods of exposure.

MeSH terms

  • Animals
  • Breast Neoplasms / drug therapy
  • Breast Neoplasms / metabolism
  • Breast Neoplasms / pathology
  • CHO Cells
  • Cells, Cultured
  • Colorectal Neoplasms / drug therapy
  • Colorectal Neoplasms / metabolism
  • Colorectal Neoplasms / pathology
  • Cricetinae
  • Cricetulus
  • DNA Damage / drug effects*
  • DNA Repair / drug effects
  • DNA Topoisomerases, Type I / chemistry
  • DNA Topoisomerases, Type I / metabolism
  • DNA Topoisomerases, Type II / chemistry
  • DNA Topoisomerases, Type II / metabolism
  • Fluorescent Antibody Technique
  • Histones / genetics
  • Histones / metabolism
  • Humans
  • Immunoassay
  • K562 Cells
  • Phenazines / pharmacology*
  • Topoisomerase I Inhibitors*
  • Topoisomerase II Inhibitors*

Substances

  • 4-methoxybenzo(a)phenazine-11-carboxylic acid (2-(dimethylamino)-1-methylethyl)amide
  • H2AX protein, human
  • Histones
  • Phenazines
  • Topoisomerase I Inhibitors
  • Topoisomerase II Inhibitors
  • XR5944
  • DNA Topoisomerases, Type I
  • DNA Topoisomerases, Type II