An analysis of phase-modulated heteronuclear dipolar decoupling sequences in solid-state nuclear magnetic resonance

J Magn Reson. 2008 Jul;193(1):77-88. doi: 10.1016/j.jmr.2008.04.024. Epub 2008 Apr 23.

Abstract

The design of variants of the swept-frequency two-pulse phase modulation sequence for heteronuclear dipolar decoupling in solid-state NMR is reported, their performance evaluated, and compared with other established sequences like TPPM and SPINAL. Simulations performed to probe the role of the homonuclear (1)H-(1)H bath show that the robustness of the decoupling schemes improves with the size of the bath. In addition, these simulations reveal that the homonuclear (1)H-(1)H bath also leads to broad baselines at high MAS rates. Results from a study of the SPINAL decoupling scheme indicate that optimisation of the starting phase and phase increment improves its performance and efficiency at high MAS rates. Additionally, experiments performed on a liquid crystal display the role of the initial phase in SPINAL-64 and sequences in the SW(f)-TPPM family.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carbon Isotopes
  • Glycine / chemistry*
  • Liquid Crystals / chemistry*
  • Magnetic Resonance Spectroscopy / methods*

Substances

  • Carbon Isotopes
  • Glycine