The stereochemical course of bromoetherification of enynes

Chem Commun (Camb). 2008 Mar 28:(12):1419-21. doi: 10.1039/b800054a. Epub 2008 Feb 20.

Abstract

Enynes undergo stereoselective syn intramolecular bromoetherification; the stereochemical course of the reaction was elucidated by X-ray crystallographic studies and by stereospecific synthesis of authentic bromoallenes.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkadienes / chemical synthesis*
  • Alkadienes / chemistry
  • Alkynes / chemistry*
  • Hydrocarbons, Brominated / chemical synthesis*
  • Hydrocarbons, Brominated / chemistry
  • Molecular Conformation
  • Stereoisomerism

Substances

  • Alkadienes
  • Alkynes
  • Hydrocarbons, Brominated