Antimicrobial and anti-inflammatory activities of a Leu/Lys-rich antimicrobial peptide with Phe-peptoid residues

Protein Pept Lett. 2007;14(10):1003-7. doi: 10.2174/092986607782541042.

Abstract

To develop a novel cell-selective antimicrobial peptide with potent anti-inflammatory activity as well as high bacterial cell selectivity, we synthesized a Leu/Lys-rich model peptide, KLW-f (KWKKLLKKfLKLfKKLLK-NH(2)) containing two Phe-peptoid residues in its middle position. KLW-f exhibited high antimicrobial activity (the MIC range: 0.5 approximately 2.0microM) against the tested six bacterial cells. In contrast, KLW-f was no cytotoxic to human red blood cells and HeLa and NIH-3T3 cells. KLW-f caused no or little dye leakage from EYPE/EYPG (7:3, w/w) vesicles (bacterial membrane-mimicking environments), indicating its bacterial-killing action is probably not due to permeabilization/disruption of bacterial cytoplasmic membranes. Furthermore, KLW-f induced a significant inhibition in LPS-stimulated NO production from mouse macrophage RAW264.7 cells at 10microg/ml. Taken together, our results suggest that KLW-f appear to have promising therapeutic potential for future development as a novel antisepsis agent as well as antimicrobial agent.

MeSH terms

  • Amino Acid Sequence
  • Animals
  • Anti-Infective Agents / chemistry*
  • Anti-Infective Agents / pharmacology
  • Anti-Infective Agents / toxicity
  • Anti-Inflammatory Agents / chemistry*
  • Anti-Inflammatory Agents / pharmacology
  • Anti-Inflammatory Agents / toxicity
  • Erythrocytes / drug effects
  • Fluoresceins / metabolism
  • Gram-Negative Bacteria / drug effects
  • Gram-Positive Bacteria / drug effects
  • HeLa Cells
  • Humans
  • Leucine / analysis*
  • Lysine / analysis*
  • Mice
  • Microbial Sensitivity Tests
  • Molecular Sequence Data
  • NIH 3T3 Cells
  • Nitric Oxide / metabolism
  • Peptides / chemistry
  • Peptides / pharmacology*
  • Peptides / toxicity
  • Peptoids / chemistry*
  • Phenylalanine / analysis*

Substances

  • Anti-Infective Agents
  • Anti-Inflammatory Agents
  • Fluoresceins
  • Peptides
  • Peptoids
  • Nitric Oxide
  • Phenylalanine
  • Leucine
  • Lysine
  • fluorexon