Fibronectin adsorption on gold, Ti-, and Ta-oxide investigated by QCM-D and RSA modelling

J Colloid Interface Sci. 2008 Apr 1;320(1):110-6. doi: 10.1016/j.jcis.2007.11.047. Epub 2007 Dec 7.

Abstract

The adsorption of fibronectin on gold, Ti-, and Ta-oxide surfaces is investigated by means of the quartz crystal microbalance with dissipation (QCM-D) technique. The surface chemistry (gold, Ti-, and Ta-oxide) is found to influence the frequency shift observed during adsorption of the fibronectin layer with the magnitude being Delta f Au>Delta f Ti-oxide approximately Delta f Ta-oxide. Corresponding variations in the dissipation change normalised to frequency change (Delta D/Delta f) for the layer are observed. The QCM-D data are further analyzed by the random sequential adsorption (RSA) model, and adsorption rate parameter ka and footprint (a) determined, which supported the trend seen in the Delta f and Delta D/Delta f values. The value of ka found by the RSA modelling of the QCM-D resonance frequency data is found to match the ratio between the mass measured by QCM-D and the mass reported by optical techniques in literature. We conclude that comparison of the adsorption rate parameter (ka) obtained by RSA modelling of the QCM-D data with ka values obtained from RSA modelling of data obtained using optical techniques can be a route to determine the degree of hydration of the adsorbed protein layer.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Fibronectins / chemistry*
  • Gold / chemistry*
  • Humans
  • Oxides / chemistry*
  • Quartz / chemistry
  • Surface Properties
  • Tantalum / chemistry*
  • Titanium / chemistry*

Substances

  • Fibronectins
  • Oxides
  • Quartz
  • Tantalum
  • Gold
  • Titanium
  • tantalum oxide