Synthesis of amino-acid derivatives and dipeptides with an original peptidase enzyme

Biomed Biochim Acta. 1991;50(10-11):S163-8.

Abstract

A peptidase from the non pathogenic Staphylococcus sp. strain BEC 299 was purified to a final specific activity of 84,400 U/mg protein. Its molecular weight is 450 kDa and optimum pH 10.0. This enzyme catalyzes the synthesis of dipeptides (aspartame) and alpha-amino acid derivatives (N-L-malyl-L-tyrosine ethyl ester). The influence of cosolvents and pH on dipeptides and alpha-amino acid derivative synthesis is described. Finally, we detail the use of the peptidase as a reagent in protease-catalyzed peptide synthesis.

MeSH terms

  • Amino Acids / chemical synthesis*
  • Amino Acids / chemistry
  • Aspartame / chemical synthesis
  • Dipeptides / chemical synthesis*
  • Dipeptides / chemistry
  • Endopeptidases / chemistry*
  • Endopeptidases / isolation & purification
  • Hydrogen-Ion Concentration
  • Staphylococcus / enzymology

Substances

  • Amino Acids
  • Dipeptides
  • Endopeptidases
  • Aspartame