Moving nanoparticles with Raman scattering

Nano Lett. 2007 Sep;7(9):2753-7. doi: 10.1021/nl0712466. Epub 2007 Aug 14.

Abstract

We show how to change optically the distance between two protein-linked gold nanoparticles by Raman-induced motion of the linker protein. Rayleigh scattering spectroscopy of the coupled-particle plasmon allows us to compare the inter-nanoparticle distance of individual protein-linked gold nanoparticle dimers before and after surface-enhanced Raman scattering (SERS). We find that low-intensity (50 microW/microm2) laser light in resonance with the nanoparticle-dimer plasmon provokes a change of the inter-nanoparticle distance on the order of 0.5 nm whenever SERS from the proteins connecting the nanoparticles can be observed.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallization / methods
  • Dose-Response Relationship, Radiation
  • Gold / chemistry*
  • Gold / radiation effects
  • Light
  • Micromanipulation / methods*
  • Motion
  • Nanostructures / chemistry*
  • Nanostructures / radiation effects*
  • Nanostructures / ultrastructure
  • Nanotechnology / methods*
  • Optical Tweezers*
  • Particle Size
  • Radiation Dosage
  • Spectrum Analysis, Raman / methods*

Substances

  • Gold