Rat brain gamma-secretase activity is highly influenced by detergents

Biochemistry. 2007 Jun 26;46(25):7647-54. doi: 10.1021/bi0621258. Epub 2007 May 31.

Abstract

Gamma-secretase is important for the development of Alzheimer's disease, since it is a crucial enzyme for the generation of the pathogenic amyloid beta-peptide (Abeta). Most data on gamma-secretase is derived from studies in cell lines overexpressing gamma-secretase components or amyloid precursor protein (APP), and since gamma-secretase is a transmembrane protein complex, detergents have been frequently used to facilitate the studies. However, no extensive comparison of the influence of different detergents at different concentrations on gamma-secretase activity in preparations from brain has been made. Here, we establish the optimal conditions for gamma-secretase activity in rat brain, using an activity assay detecting endogenous production of the APP intracellular domain, which is generated when gamma-secretase cleaves the APP C-terminal fragments. We performed a subcellular fractionation and noted the highest gamma-secretase activity in the 100000g pellet and that the optimal pH was around 7. We found that gamma-secretase was active for at least 16 h at 37 degrees C and that the endogenous substrate levels were sufficient for activity measurements. The highest activity was obtained in 0.4% CHAPSO, which is slightly below the critical micelle concentration (0.5%) for this detergent, but the complex was not solubilized efficiently at this concentration. On the other hand, 1% CHAPSO solubilized a substantial amount of the gamma-secretase components, but the activity was low. The activity was fully restored by diluting the sample to 0.4% CHAPSO. Therefore, using 1% CHAPSO for solubilization and subsequently diluting the sample to 0.4% is an appropriate procedure for obtaining a soluble, highly active gamma-secretase from rat brain.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amyloid Precursor Protein Secretases / metabolism*
  • Amyloid beta-Protein Precursor / chemistry
  • Animals
  • Brain / enzymology*
  • Cell Membrane / chemistry
  • Cholic Acids / pharmacology*
  • Detergents / pharmacology*
  • Dose-Response Relationship, Drug
  • Hydrogen-Ion Concentration
  • Male
  • Protein Structure, Tertiary
  • Rats
  • Rats, Sprague-Dawley
  • Solubility
  • Subcellular Fractions / enzymology
  • Temperature
  • Time Factors

Substances

  • Amyloid beta-Protein Precursor
  • Cholic Acids
  • Detergents
  • chapso
  • Amyloid Precursor Protein Secretases