Determination of lysozyme at the nanogram level by a resonance light-scattering technique with functionalized CdTe nanoparticles

Anal Sci. 2007 Mar;23(3):331-5. doi: 10.2116/analsci.23.331.

Abstract

Nanoparticles of cadmium telluride coated with mercaptoacetic acid were prepared in the water phase. Further, an assay of lysozyme with a sensitivity at the nanogram level is proposed. At pH 7.28, lysozyme with positive charges can interact with CdTe nanoparticles. The resonance light-scattering (RLS) signals of functionalized nano-CdTe were greatly enhanced by lysozyme in the region of 300-600 nm, characterized with peaks located at 367, 470 and 533 nm. A linear relationship could be established between the enhanced RLS intensity and the lysozyme concentration in the range of 0.06-4.0 microg mL-1. The limit of detection was 9.5 ng mL-1. The contents of lysozyme were determined with recoveries of 95.6-104.8% and RSD of 1.5-2.3%, respectively. This method is sensitive, rapid, accurate and simple, and provides a new and reliable means for the quantity determination of lysozyme.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Buffers
  • Cadmium Compounds / chemistry*
  • Colloids
  • Hydrogen-Ion Concentration
  • Muramidase / analysis*
  • Muramidase / chemistry
  • Nanoparticles / chemistry*
  • Osmolar Concentration
  • Tellurium / chemistry*
  • Time Factors

Substances

  • Buffers
  • Cadmium Compounds
  • Colloids
  • Muramidase
  • Tellurium
  • cadmium telluride