Dynamic redox control of NF-kappaB through glutaredoxin-regulated S-glutathionylation of inhibitory kappaB kinase beta

Proc Natl Acad Sci U S A. 2006 Aug 29;103(35):13086-91. doi: 10.1073/pnas.0603290103. Epub 2006 Aug 17.

Abstract

The transcription factor NF-kappaB, a central regulator of immunity, is subject to regulation by redox changes. We now report that cysteine-179 of the inhibitory kappaB kinase (IKK) beta-subunit of the IKK signalosome is a central target for oxidative inactivation by means of S-glutathionylation. S-glutathionylation of IKK-beta Cys-179 is reversed by glutaredoxin (GRX), which restores kinase activity. Conversely, GRX1 knockdown sensitizes cells to oxidative inactivation of IKK-beta and dampens TNF-alpha-induced IKK and NF-kappaB activation. Primary tracheal epithelial cells from Glrx1-deficient mice display reduced NF-kappaB DNA binding, RelA nuclear translocation, and MIP-2 (macrophage inflammatory protein 2) and keratinocyte-derived chemokine production in response to LPS. Collectively, these findings demonstrate the physiological relevance of the S-glutathionylation-GRX redox module in controlling the magnitude of activation of the NF-kappaB pathway.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Cells, Cultured
  • Chemokine CXCL2
  • Chemokines / biosynthesis
  • Cysteine / metabolism
  • Glutaredoxins
  • Glutathione / metabolism*
  • Hydrogen Peroxide / pharmacology
  • I-kappa B Kinase / antagonists & inhibitors*
  • Keratinocytes / cytology
  • Keratinocytes / drug effects
  • Lipopolysaccharides / immunology
  • Mice
  • Mice, Inbred C57BL
  • Monokines / metabolism
  • NF-kappa B / metabolism*
  • Oxidation-Reduction / drug effects
  • Oxidoreductases / deficiency
  • Oxidoreductases / metabolism*
  • Protein Subunits / metabolism
  • Respiratory System / cytology
  • Respiratory System / drug effects
  • Sulfenic Acids / metabolism

Substances

  • Chemokine CXCL2
  • Chemokines
  • Glrx protein, mouse
  • Glutaredoxins
  • Lipopolysaccharides
  • Monokines
  • NF-kappa B
  • Protein Subunits
  • Sulfenic Acids
  • Hydrogen Peroxide
  • Oxidoreductases
  • I-kappa B Kinase
  • Glutathione
  • Cysteine