On the connection between optical absorption/extinction and SERS enhancements

Phys Chem Chem Phys. 2006 Jul 14;8(26):3083-7. doi: 10.1039/b605292d. Epub 2006 Jun 8.

Abstract

Several aspects of the connection between the absorption/extinction spectra and the enhancement in surface enhanced Raman scattering (SERS) are analyzed and discussed. It is shown that in many standard situations the spatial distribution of the resonance plays a role for the difference between extinction/absorption and SERS enhancement and that the connection between both can be very indirect and, in many cases, misleading. This clarifies several misconceptions often found in the literature.

MeSH terms

  • Absorption
  • Algorithms*
  • Computer Simulation
  • Light*
  • Models, Chemical*
  • Optics and Photonics
  • Reproducibility of Results
  • Scattering, Radiation
  • Sensitivity and Specificity
  • Spectrum Analysis, Raman / methods*
  • Surface Plasmon Resonance / methods*