Aqua(thiosulfato-kappa2O,S)[2,4,6-tri-2-pyridyl-1,3,5-triazine-kappa3N2,N1,N6]zinc(II) hemihydrate

Acta Crystallogr C. 2006 May;62(Pt 5):m192-4. doi: 10.1107/S0108270106010560. Epub 2006 Apr 13.

Abstract

The title compound, [Zn(S2O3)(C18H12N6)(H2O)].0.5H2O, contains two almost identical independent monomeric moieties composed of an octahedral Zn centre coordinated by a tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine (tpt) ligand, one aqua ligand and an O,S-chelating thiosulfate anion. The structure is stabilized by a solvent water molecule. Multiple strong hydrogen bonds with additional weaker pi-pi interactions between tpt groups define a multiple column spatial organization.