One-dimensional mu-chloromanganese(II)-tetrathiafulvalene (TTF) coordination compound

Chunyang Jia; Shi-Xia Liu; Christina Ambrus; Antonia Neels; Gaël Labat; Silvio Decurtins

doi:10.1021/ic060056f

One-dimensional mu-chloromanganese(II)-tetrathiafulvalene (TTF) coordination compound

Inorg Chem. 2006 Apr 17;45(8):3152-4. doi: 10.1021/ic060056f.

Authors

Chunyang Jia¹, Shi-Xia Liu, Christina Ambrus, Antonia Neels, Gaël Labat, Silvio Decurtins

Affiliation

¹ Departement für Chemie und Biochemie, Universität Bern, Freiestrasse 3, CH-3012 Bern, Switzerland.

PMID: 16602768
DOI: 10.1021/ic060056f

Abstract

A new tetrathiafulvalene derivative 1 bearing a single pyridine group and its coordination complex 2, with stoichiometry [Mn(mu-Cl)Cl(1)2(CH3OH)]n, have been synthesized and fully characterized. The complex 2 shows an extended chain structure, which is potentially favorable for electrical conductivity. Notably, this is the first monohalogen-bridged Mn(II) polymer exhibiting a moderate antiferromagnetic coupling between the Mn(II) centers.