First metal azide complex with isonicotinate as a bridging ligand showing new net topology: hydrothermal synthesis, structure, and magnetic properties

Fu-Chen Liu; Yong-Fei Zeng; Jiao Jiao; Xian-He Bu; Joan Ribas; Stuart R Batten

doi:10.1021/ic051896h

First metal azide complex with isonicotinate as a bridging ligand showing new net topology: hydrothermal synthesis, structure, and magnetic properties

Inorg Chem. 2006 Apr 3;45(7):2776-8. doi: 10.1021/ic051896h.

Authors

Fu-Chen Liu¹, Yong-Fei Zeng, Jiao Jiao, Xian-He Bu, Joan Ribas, Stuart R Batten

Affiliation

¹ Department of Chemistry, Nankai University, Tianjin 300071, China.

PMID: 16562932
DOI: 10.1021/ic051896h

Abstract

A new 3D azido-bridged coordination polymer, [Co1.5(N3)(OH)(Isonic)]n (1), has been synthesized and characterized and its magnetic properties studied. Isonicotinate acts as a bridging coligand in this complex. In 1, all of the ligands take tridentate bridging coordination modes, and the overall structure of 1 exhibits a new 3,6-connected net topology.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Azides / chemistry*
Cobalt / chemistry*
Isonicotinic Acids / chemistry*
Ligands
Magnetics*
Models, Molecular
Molecular Structure
Organometallic Compounds* / chemical synthesis
Organometallic Compounds* / chemistry
Temperature*

Substances

Azides
Isonicotinic Acids
Ligands
Organometallic Compounds
Cobalt