Microwave-assisted parallel synthesis of a 14-helical beta-peptide library

J Comb Chem. 2006 Jan-Feb;8(1):58-65. doi: 10.1021/cc0501099.

Abstract

To facilitate the preparation of beta-peptide libraries in parallel, we have adapted reaction conditions for the solid-phase synthesis of 14-helical beta-peptides for use in a multimode microwave reactor. The low temperature/pressure requirements of microwave-assisted beta-peptide synthesis were found to be compatible with multiwell filter plates composed of polypropylene. Microwave heating of the 96-well plate was sufficiently homogeneous to allow the rapid preparation of a beta-peptide library in acceptable purity.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Chromatography, High Pressure Liquid
  • Combinatorial Chemistry Techniques* / instrumentation
  • Combinatorial Chemistry Techniques* / methods
  • Hydrogen Bonding
  • Microwaves*
  • Molecular Structure
  • Peptide Library
  • Peptides / chemical synthesis*
  • Peptides / chemistry
  • Protein Structure, Secondary

Substances

  • Peptide Library
  • Peptides