Abstract
We synthesized a water-soluble, long-wavelength K(+) sensor, TAC-Red, consisting of triazacryptand coupled to 3,6-bis(dimethylamino)xanthylium, whose fluorescence increased 14-fold at 0-50 mM K(+) with K(+)-to-Na(+) selectivity >30. We visualized K(+) waves in TAC-Red-stained brain cortex in mice during spreading depression, with velocity 4.4 +/- 0.5 mm/min, and K(+) release and reuptake half-times (t(1/2)) of 12 +/- 2 and 32 +/- 4 s, respectively. Aquaporin-4 (AQP4) deletion slowed K(+) reuptake about twofold, suggesting AQP4-dependent K(+) uptake by astroglia.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, P.H.S.
MeSH terms
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Animals
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Aquaporin 4 / genetics
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Aquaporin 4 / metabolism
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Astrocytes / metabolism
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Aza Compounds / analysis
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Aza Compounds / chemistry
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Cerebral Cortex / metabolism*
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Fluorescent Dyes / analysis*
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Fluorescent Dyes / chemistry
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Heterocyclic Compounds, 3-Ring / analysis
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Heterocyclic Compounds, 3-Ring / chemistry
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Mice
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Mice, Knockout
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Molecular Structure
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Potassium / analysis*
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Potassium / metabolism
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Solubility
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Time Factors
Substances
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Aqp4 protein, mouse
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Aquaporin 4
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Aza Compounds
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Fluorescent Dyes
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Heterocyclic Compounds, 3-Ring
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TAC-Red
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Potassium