Dithiadiazuliporphyrin: facile generation of carbaporphyrinoid cation radical and dication

Natasza Sprutta; Marta Swiderska; Lechosław Latos-Grazyński

doi:10.1021/ja053723x

Dithiadiazuliporphyrin: facile generation of carbaporphyrinoid cation radical and dication

J Am Chem Soc. 2005 Sep 28;127(38):13108-9. doi: 10.1021/ja053723x.

Authors

Natasza Sprutta¹, Marta Swiderska, Lechosław Latos-Grazyński

Affiliation

¹ Department of Chemistry, University of Wrocław, Wrocław 50 383, Poland.

PMID: 16173714
DOI: 10.1021/ja053723x

Abstract

Dithiadiazuliporphyrin is a nonaromatic porphyrinoid, readily and reversibly oxidizable to its cation radical and to the unprecedented aromatic carbaporphyrinoid dication, which can be viewed as a 21,23-dicarba-22,24-dithiaporphyrin with two fused tropylium rings.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Azulenes
Cations / chemistry
Crystallography, X-Ray
Cycloheptanes / chemical synthesis*
Cycloheptanes / chemistry
Free Radicals / chemistry
Models, Molecular
Molecular Structure
Oxidation-Reduction
Porphyrins / chemical synthesis*
Porphyrins / chemistry

Substances

Azulenes
Cations
Cycloheptanes
Free Radicals
Porphyrins
azulene