Comparative enzymology of 11beta-hydroxysteroid dehydrogenase type 1 from six species

J Mol Endocrinol. 2005 Aug;35(1):89-101. doi: 10.1677/jme.1.01736.

Abstract

11beta-Hydroxysteroid dehydrogenase type 1 (11beta-HSD1), catalyzing the intracellular activation of cortisone to cortisol, is currently considered a promising target to treat patients with metabolic syndrome; hence, there is considerable interest in the development of selective inhibitors. For preclinical tests of such inhibitors, the characteristics of 11beta-HSD1 from the commonly used species have to be known. Therefore, we determined differences in substrate affinity and inhibitor effects for 11beta-HSD1 from six species. The differences in catalytic activities with cortisone and 11-dehydrocorticosterone were rather modest. Human, hamster and guinea-pig 11beta-HSD1 displayed the highest catalytic efficiency in the oxoreduction of cortisone, while mouse and rat showed intermediate and dog the lowest activity. Murine 11beta-HSD1 most efficiently reduced 11-dehydrocorticosterone, while the enzyme from dog showed lower activity than those from the other species. 7-ketocholesterol (7KC) was stereospecifically converted to 7beta-hydroxycholesterol by recombinant 11beta-HSD1 from all species analyzed except hamster, which showed a slight preference for the formation of 7alpha-hydroxycholesterol. Importantly, guinea-pig and canine 11beta-HSD1 displayed very low 7-oxoreductase activities. Furthermore, we demonstrate significant species-specific variability in the potency of various 11beta-HSD1 inhibitors, including endogenous compounds, natural chemicals and pharmaceutical compounds. The results suggest significant differences in the three-dimensional organization of the hydrophobic substrate-binding pocket of 11beta-HSD1, and they emphasize that species-specific variability must be considered in the interpretation of results obtained from different animal experiments. The assessment of such differences, by cell-based test systems, may help to choose the appropriate animal for safety and efficacy studies of novel potential drug candidates.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • 11-beta-Hydroxysteroid Dehydrogenase Type 1 / antagonists & inhibitors
  • 11-beta-Hydroxysteroid Dehydrogenase Type 1 / chemistry
  • 11-beta-Hydroxysteroid Dehydrogenase Type 1 / genetics
  • 11-beta-Hydroxysteroid Dehydrogenase Type 1 / metabolism*
  • Amino Acid Sequence
  • Animals
  • Base Sequence
  • Catalytic Domain
  • Cell Line
  • Cloning, Molecular
  • Corticosterone / analogs & derivatives
  • Corticosterone / metabolism
  • Cortisone / metabolism
  • Cricetinae
  • DNA, Complementary / genetics
  • Dogs
  • Enzyme Inhibitors / pharmacology
  • Guinea Pigs
  • Humans
  • In Vitro Techniques
  • Kinetics
  • Mice
  • Models, Molecular
  • Molecular Sequence Data
  • Oxidation-Reduction
  • Rats
  • Recombinant Proteins / antagonists & inhibitors
  • Recombinant Proteins / chemistry
  • Recombinant Proteins / genetics
  • Recombinant Proteins / metabolism
  • Sequence Homology, Amino Acid
  • Species Specificity
  • Substrate Specificity

Substances

  • DNA, Complementary
  • Enzyme Inhibitors
  • Recombinant Proteins
  • 11-beta-Hydroxysteroid Dehydrogenase Type 1
  • 11-dehydrocorticosterone
  • Cortisone
  • Corticosterone