Assays for mechanistic investigations of protein/histone acetyltransferases

Methods. 2005 Aug;36(4):321-31. doi: 10.1016/j.ymeth.2005.03.002.

Abstract

Protein/histone acetyltransferases (PATs/HATs) have been implicated in a number of cellular functions including gene regulation, DNA synthesis, and repair. This paper reviews methods that can be used to quantitatively determine the activity and ultimately the catalytic/kinetic mechanism of PAT/HATs in vitro. Two methods will be described in detail. The first method is a filter-binding assay that measures the transfer of radiolabeled acetate from acetyl-CoA to protein. The second method is a continuous, spectroscopic, enzyme-coupled assay that links the PAT/HAT reaction to the reduction of NAD+ by pyruvate or alpha-ketoglutarate dehydrogenase. Both methods are highly applicable in determining steady-state reaction rates, and obtaining the kinetic constants Vmax, Km, and V/K from substrate saturation curves. We describe a new application of the filter-binding assay to determine the kinetic parameters for HATs using low concentrations of nucleosomal substrates.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, P.H.S.
  • Review

MeSH terms

  • Acetyl Coenzyme A / chemistry
  • Acetyltransferases / chemistry*
  • Acetyltransferases / metabolism
  • Algorithms
  • Animals
  • Catalysis
  • Cellulose / analogs & derivatives
  • Cellulose / chemistry
  • Clinical Laboratory Techniques*
  • Filtration
  • Histone Acetyltransferases
  • Humans
  • Kinetics
  • Micropore Filters
  • Models, Chemical
  • NAD / chemistry
  • Spectrophotometry
  • Tritium / chemistry

Substances

  • NAD
  • Tritium
  • Acetyl Coenzyme A
  • Cellulose
  • phosphocellulose
  • Acetyltransferases
  • Histone Acetyltransferases