High-performance liquid chromatography with post-column derivatisation and fluorescence detection for sensitive determination of aflatoxin M1 in milk and cheese

J Chromatogr A. 2005 Aug 12;1083(1-2):219-22. doi: 10.1016/j.chroma.2005.06.039.

Abstract

A new HPLC method with fluorescence detection using pyridinium hydrobromide perbromide as a post-column derivatising agent has been developed to determine aflatoxin M1 in milk and cheese. The detection limits were 1 ng/kg for milk and 5 ng/kg for cheese. The calibration curve was linear from 0.001 to 0.1 ng injected. The method includes a preliminary C18-SPE clean-up and the average recoveries of Aflatoxin M1 from milk and cheese, spiked at levels of 25-75 ng/kg and 100-300 ng/kg, respectively, were 90 and 76%; the precision (RSDr) ranged from 1.7 to 2.6% for milk and from 3.5 to 6.5% for cheese. The method is rapid, easily automatable and therefore useful for accurate and precise screening of aflatoxin M1 in milk and cheese.

Publication types

  • Validation Study

MeSH terms

  • Aflatoxin M1 / analysis*
  • Animals
  • Cattle
  • Cheese / analysis*
  • Chromatography, High Pressure Liquid / methods*
  • Female
  • Milk / chemistry*
  • Spectrometry, Fluorescence / methods

Substances

  • Aflatoxin M1