Diacetatobis(2-aminobenzothiazole-kappaN)cobalt(II)

Acta Crystallogr C. 2005 Jul;61(Pt 7):m342-3. doi: 10.1107/S0108270105016811. Epub 2005 Jun 22.

Abstract

The title complex, [Co(C2H3O2)2(C7H6N2S)2], contains a Co centre with a slightly distorted tetrahedral coordination geometry, involving two acetate ligands and two N atoms from the thiazole moiety [Co-O = 2.0025 (14) and 1.9953 (16) A, and Co-N = 2.0524 (18) and 2.0568 (18) A]. The interplanar angle between the two benzothiazole moieties is 77.86 (3) degrees . The amine groups, acting as donors, participate in intra- and intermolecular N-H...O hydrogen bonds, with N...O distances in the range 2.806 (2)-2.857 (2) A.

MeSH terms

  • Crystallography, X-Ray
  • Hydrogen Bonding
  • Models, Molecular
  • Molecular Structure
  • Organometallic Compounds / chemistry*
  • Thiazoles / chemistry*

Substances

  • Organometallic Compounds
  • Thiazoles
  • diacetatobis(2-aminobenzothiazole-kappaN)cobalt(II)