A sensitive assay of amoxicillin in mouse serum and broncho-alveolar lavage fluid by liquid-liquid extraction and reversed-phase HPLC

J Pharm Biomed Anal. 2005 Sep 15;39(3-4):648-52. doi: 10.1016/j.jpba.2005.04.021.

Abstract

A sensitive and simple high-performance liquid chromatography (HPLC) method was developed and validated for the analysis of amoxicillin in mouse serum and broncho-alveolar lavage (BAL) fluid. One hundred microlitres of sample were needed for the assay. Sample processing was carried out with liquid-liquid extraction. Cefadroxil was used as an internal standard. The chromatographic separation was achieved on a C18 reversed-phase column with a mobile phase consisting of phosphate buffer, 1-octanesulphonic acid sodium salt and acetonitrile. The detection was conducted at 210 nm. The ranges of the standard curves were 0.2-20 and 0.05-5 microg/ml for serum and BAL samples, respectively. The recoveries of amoxicillin from serum and normal saline were 87 and 88%, respectively. The coefficients of variation were 1.78-6.13% for intra-day and 0.82-6.42% for inter-day analyses. The accuracy was within 100+/-6%. This method was successfully applied to analyze amoxicillin in mouse serum and BAL samples from a pharmacokinetic study.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amoxicillin / analysis*
  • Amoxicillin / blood*
  • Amoxicillin / pharmacokinetics
  • Animals
  • Anti-Bacterial Agents / analysis*
  • Anti-Bacterial Agents / blood
  • Anti-Bacterial Agents / pharmacokinetics*
  • Bronchoalveolar Lavage Fluid*
  • Calibration
  • Cefadroxil / analysis
  • Chromatography
  • Chromatography, High Pressure Liquid / methods*
  • Drug Industry / methods
  • Mice
  • Mice, Inbred ICR
  • Quality Control
  • Reproducibility of Results
  • Sensitivity and Specificity
  • Spectrophotometry, Ultraviolet
  • Time Factors
  • Ultraviolet Rays

Substances

  • Anti-Bacterial Agents
  • Cefadroxil
  • Amoxicillin