Synthesis and near infrared luminescence of a tetrametallic Zn2Yb2 architecture from a trinuclear Zn3L2 Schiff base complex

Dalton Trans. 2005 Mar 7:(5):849-51. doi: 10.1039/b416695g. Epub 2005 Feb 2.

Abstract

Near infrared luminescence is observed in tetrametallic [Zn2Yb2L2(mu-OH)2Cl4].2MeCN which is obtained from the Zn3 Schiff-base complex [Zn3L2(NO3)2].MeOH, (H2L =N,N'-bis(5-bromo-3-methoxysalicylidene)propylene-1,3-diamine).

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography, X-Ray
  • Hydrogen Bonding
  • Infrared Rays
  • Ligands
  • Luminescence*
  • Molecular Conformation
  • Organometallic Compounds / chemical synthesis*
  • Organometallic Compounds / chemistry*
  • Organometallic Compounds / metabolism
  • Photochemistry
  • Schiff Bases*
  • Ytterbium / chemistry*
  • Ytterbium / metabolism
  • Zinc / chemistry*
  • Zinc / metabolism

Substances

  • Ligands
  • Organometallic Compounds
  • Schiff Bases
  • Zinc
  • Ytterbium