Development of a novel biomaterial, hydroxyapatite/collagen (HAp/Col) composite for medical use

Biomed Mater Eng. 2005;15(1-2):29-41.

Abstract

A hydroxyapatite/type I collagen (HAp/Col) composite, aligning hydroxyapatite nano-crystals along collagen molecules, has been synthesized. The biocompatibility, osteoconductivity and efficacy as an rhBMP-2 carrier of this novel biomaterial implanted in the weight-bearing site have been examined. The HAp/Col implants adsorbing 0 or 400 microg/ml of rhBMP-2 were implanted into bone defects of tibiae in 3 beagle dogs and fixed according to the Ilizarov method. As a control, bone defects of 20 mm remaining in 2 beagle dogs and the dogs were allowed to walk using a Ilizarov external skeletal fixator. The radiological and histological findings suggest that the implants induce bone remodeling units and are a superior carrier of rhBMP-2 due to the stimulation of early callus and new bone formation. As a next step, anterior fusion was carried out on 6 beagle dogs with the implants adsorbing 400 microg/ml of rhBMP-2, and 9 dogs with the implants without rhBMP-2. In 3 dogs of the rhBMP-treated group, as well as 6 dogs of the non-rhBMP-treated group, the implant was fixed with a poly-L-lactide plate. Histological and radiographical analysis suggest that enhancement of callus formation and bone bridging by rhBMP-treatment is effective to prevent collapse of the implant.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Bone Morphogenetic Protein 2
  • Bone Morphogenetic Proteins / administration & dosage
  • Bone Substitutes*
  • Cervical Vertebrae / diagnostic imaging
  • Cervical Vertebrae / pathology
  • Cervical Vertebrae / physiopathology
  • Cervical Vertebrae / surgery
  • Collagen / chemistry*
  • Dogs
  • Drug Delivery Systems / methods
  • Durapatite / chemistry*
  • Fracture Healing / drug effects
  • Fracture Healing / physiology
  • Fractures, Bone / drug therapy
  • Fractures, Bone / pathology*
  • Fractures, Bone / physiopathology
  • Fractures, Bone / surgery*
  • Implants, Experimental*
  • Male
  • Manufactured Materials
  • Materials Testing
  • Osseointegration / drug effects
  • Osseointegration / physiology
  • Osteogenesis / drug effects
  • Osteogenesis / physiology
  • Radiography
  • Radius / diagnostic imaging
  • Radius / pathology
  • Radius / physiopathology
  • Radius / surgery
  • Spinal Fusion / methods*
  • Transforming Growth Factor beta / administration & dosage
  • Treatment Outcome
  • Ulna / diagnostic imaging
  • Ulna / pathology
  • Ulna / physiopathology
  • Ulna / surgery

Substances

  • Bone Morphogenetic Protein 2
  • Bone Morphogenetic Proteins
  • Bone Substitutes
  • Transforming Growth Factor beta
  • Collagen
  • Durapatite