Magnetic anisotropy of a high-spin octanuclear nickel(II) complex with a meso-helicate core

Inorg Chem. 2004 Nov 29;43(24):7594-6. doi: 10.1021/ic048965x.

Abstract

The octanickel(II) cluster 2b has been synthesized from the novel ferromagnetically coupled dinickel(II) metallacryptand 1b assembled from the m-phenylene-bis(oxamate) ligand. Complex 2b exhibits a dimer-of-tetramers structure, with two oxamate-bridged propeller-shaped tetranuclear units connected through three meta-substituted phenylenediamidate bridges, giving a metallacryptand core of the meso-helicate type. Complex 2b behaves as a ferromagnetically coupled dimer of two S=2 Ni(II)4 units with appreciable magnetic anisotropy.