Electrogeneration of a biotinylated poly(pyrrole-ruthenium(II)) film for the construction of photoelectrochemical immunosensor

Chem Commun (Camb). 2004 Nov 7:(21):2472-3. doi: 10.1039/b410727f. Epub 2004 Sep 17.

Abstract

A biotinylated photosensitive polymer was electrogenerated from on a ruthenium complex bearing biotin and pyrrole groups; the resulting polypyrrolic film allowed the bioaffine immobilisation of avidin and biotinylated cholera toxin and the photoelectrochemical detection of the corresponding antibody.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Avidin / chemistry
  • Biosensing Techniques / methods*
  • Biotin / chemistry
  • Biotinylation
  • Cholera Toxin / chemistry
  • Electrochemistry
  • Membranes, Artificial*
  • Molecular Structure
  • Organometallic Compounds / chemistry*
  • Photochemistry
  • Polymers / chemical synthesis
  • Polymers / chemistry*
  • Pyrroles / chemical synthesis
  • Pyrroles / chemistry*
  • Ruthenium / chemistry*
  • Surface Properties

Substances

  • Membranes, Artificial
  • Organometallic Compounds
  • Polymers
  • Pyrroles
  • Avidin
  • polypyrrole
  • Biotin
  • Ruthenium
  • Cholera Toxin