Studies on 1H NMR, infrared and fluorescence spectra of rare earth complexes with a new binaphthylamide

Ya-Wen Wang; Wei-Sheng Liu; Ning Tang; Min-Yu Tan

doi:10.1016/j.saa.2003.12.023

Studies on 1H NMR, infrared and fluorescence spectra of rare earth complexes with a new binaphthylamide

Spectrochim Acta A Mol Biomol Spectrosc. 2004 Sep;60(11):2459-63. doi: 10.1016/j.saa.2003.12.023.

Authors

Ya-Wen Wang¹, Wei-Sheng Liu, Ning Tang, Min-Yu Tan

Affiliation

¹ Department of Chemistry and National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, PR China.

PMID: 15294228
DOI: 10.1016/j.saa.2003.12.023

Abstract

Solid complexes of lanthanide picrates with N,N-dibenzyl-2-[2'-[(dibenzylcarbamoyl)-methoxy]-[1,1']binaphthalenyl-2-yloxy]-acetamide (L), [Ln(pic)(3)L] (Ln = La, Nd, Eu, Gd, Tb, Dy, Y), have been prepared and characterized by elemental analysis, IR, 1H NMR, UV-Vis spectra and conductivity measurements. The fluorescence property of the europium complex in solid state and in CHCl(3), acetone, AcOEt and DMF was studied.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Acetamides / chemistry*
Lanthanoid Series Elements / chemistry*
Ligands
Magnetic Resonance Spectroscopy
Spectrometry, Fluorescence
Spectrophotometry, Infrared

Substances

Acetamides
Lanthanoid Series Elements
Ligands